Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo 6 Cl 8 }Cl 5 □] − (□ = lacuna) - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2023

Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo 6 Cl 8 }Cl 5 □] − (□ = lacuna)

Résumé

The lacunary monocharged anion [{Mo6Cli8}Cla5□a]− presents concomitantly a strongly electrophilic site and a nucleophilic one. This Janus character in terms of reactivity is confirmed by its gas phase reaction with [Br6Cs4K]− to form [{Mo6Cli8}Cla5Bra]2− and by its unusual self-reactivity leading to [{Mo6Cli8}Cla6]2− dianions.
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hal-04087734 , version 1 (11-05-2023)

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Paternité - Pas d'utilisation commerciale

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Antoine Denis, Nina Tymínska, Thomas Delhaye, Yann Molard, Pascal Gerbaux, et al.. Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo 6 Cl 8 }Cl 5 □] − (□ = lacuna). Chemical Communications, 2023, 59, pp.6243-6246. ⟨10.1039/D3CC01187A⟩. ⟨hal-04087734⟩
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