Application of Palladium-Catalyzed C(sp(2))-H Bond Arylation to the Synthesis of Polycyclic (Hetero)Aromatics - Université de Rennes Access content directly
Journal Articles Chem Year : 2019

Application of Palladium-Catalyzed C(sp(2))-H Bond Arylation to the Synthesis of Polycyclic (Hetero)Aromatics

Abstract

Recently, the use of the palladium-catalyzed inter-and/or intra-molecular C-H bond arylations in the building of various π-extended (hetero)aromatic structures has emerged as a suitable alternative to the previous multi-steps synthesis. Such new methodology even allowed to prepare unprecedented π-extended molecules owing a perfect control of the reaction sites. This review gives an overview of various synthesis of Polycyclic Aromatic Hydrocarbons (PAHs) and PolyCyclic Heteroaromatics (PCHs) with planar, bowl-shaped, and helical structures prepared in high efficiency and selectivity via Pd-catalyzed C-H bond arylations.
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Dates and versions

hal-02278410 , version 1 (25-11-2019)

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Wided Hagui, Henri Doucet, Jean-François Soulé. Application of Palladium-Catalyzed C(sp(2))-H Bond Arylation to the Synthesis of Polycyclic (Hetero)Aromatics. Chem, 2019, 5 (8), pp.2006-2078. ⟨10.1016/j.chempr.2019.06.005⟩. ⟨hal-02278410⟩
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