%0 Journal Article %T Application of Palladium-Catalyzed C(sp(2))-H Bond Arylation to the Synthesis of Polycyclic (Hetero)Aromatics %+ Institut des Sciences Chimiques de Rennes (ISCR) %A Hagui, Wided %A Doucet, Henri %A Soulé, Jean-François %Z CNRS, Univ. Rennes 1, Rennes Metropole %Z Region Bretagne (Boost'Europe) %< avec comité de lecture %@ 2451-9294 %J Chem %I Cell Press %V 5 %N 8 %P 2006-2078 %8 2019-08-08 %D 2019 %R 10.1016/j.chempr.2019.06.005 %Z Chemical SciencesJournal articles %X Recently, the use of the palladium-catalyzed inter-and/or intra-molecular C-H bond arylations in the building of various π-extended (hetero)aromatic structures has emerged as a suitable alternative to the previous multi-steps synthesis. Such new methodology even allowed to prepare unprecedented π-extended molecules owing a perfect control of the reaction sites. This review gives an overview of various synthesis of Polycyclic Aromatic Hydrocarbons (PAHs) and PolyCyclic Heteroaromatics (PCHs) with planar, bowl-shaped, and helical structures prepared in high efficiency and selectivity via Pd-catalyzed C-H bond arylations. %G English %2 https://univ-rennes.hal.science/hal-02278410/document %2 https://univ-rennes.hal.science/hal-02278410/file/Soule_et%20al_2019_Application%20of%20Palladium-Catalyzed.pdf %L hal-02278410 %U https://univ-rennes.hal.science/hal-02278410 %~ UNIV-RENNES1 %~ CNRS %~ INSA-RENNES %~ ENSC-RENNES %~ ISCR %~ SCR_OMC2012 %~ ISCR-OMC %~ STATS-UR1 %~ UR1-SPM %~ INC-CNRS %~ UR1-UFR-SPM %~ UR1-HAL %~ UR1-SDLM %~ TEST-UR-CSS %~ UNIV-RENNES %~ INSA-GROUPE %~ TEST-HALCNRS %~ UR1-MMS %~ TEST2-HALCNRS