Application of Palladium-Catalyzed C(sp(2))-H Bond Arylation to the Synthesis of Polycyclic (Hetero)Aromatics
Abstract
Recently, the use of the palladium-catalyzed inter-and/or intra-molecular C-H bond arylations in the building of various π-extended (hetero)aromatic structures has emerged as a suitable alternative to the previous multi-steps synthesis. Such new methodology even allowed to prepare unprecedented π-extended molecules owing a perfect control of the reaction sites. This review gives an overview of various synthesis of Polycyclic Aromatic Hydrocarbons (PAHs) and PolyCyclic Heteroaromatics (PCHs) with planar, bowl-shaped, and helical structures prepared in high efficiency and selectivity via Pd-catalyzed C-H bond arylations.
Domains
Chemical Sciences
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Soule_et al_2019_Application of Palladium-Catalyzed.pdf (3.28 Mo)
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