Gold-Catalyzed Synthesis of Substituted 3-Trifluoromethylpyrroles from Mesylated Amino Trifluoromethylpropargylic Alcohols - Université de Rennes Access content directly
Journal Articles Journal of Organic Chemistry Year : 2017

Gold-Catalyzed Synthesis of Substituted 3-Trifluoromethylpyrroles from Mesylated Amino Trifluoromethylpropargylic Alcohols

Abstract

A series of substituted 3-trifluoromethylpyrroles was obtained from trifluoromethylamino-ynol derivatives via a gold-catalyzed cyclization. Using fluorinated starting materials, after mesylation, allowed for the desired compounds to be obtained in good yields under mild conditions.
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hal-01680989 , version 1 (02-03-2018)

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Benjamin Guieu, Myriam Le Roch, Michèle David, Nicolas Gouault. Gold-Catalyzed Synthesis of Substituted 3-Trifluoromethylpyrroles from Mesylated Amino Trifluoromethylpropargylic Alcohols. Journal of Organic Chemistry, 2017, 82 (24), pp.13708-13713. ⟨10.1021/acs.joc.7b02567⟩. ⟨hal-01680989⟩
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