How the Anchoring Site on Two Extended Tetrathiafulvalenes Impacts the Electronic Communication through a Bis(acetylide)ruthenium Linker - Université de Rennes Access content directly
Journal Articles Organometallics Year : 2017

How the Anchoring Site on Two Extended Tetrathiafulvalenes Impacts the Electronic Communication through a Bis(acetylide)ruthenium Linker

Abstract

The interplay between two extended tetrathiafulvalenes connected, from either the dithiole rings or the anthraquinodimethane moieties, through a bis(acetylide) ruthenium linker has been studied within the novel complexes trans-[Ru(C CDTTFAQ)(2)(dppe)(2)] and trans-[Ru(C CATTFAQ)(2)(dppe)(2)]. Cyclic voltammetry and spectroelectrochemical investigations show that the organic and inorganic electrophores are electronically coupled within these complexes. Moreover, the electronic. communication between the two organic electrophores depends on the localization of the anchoring site of the organometallic bis(acetylide) ruthenium linker on the organic electrophores.
Fichier principal
Vignette du fichier
PubliDLorcy Organometallics.pdf (814.62 Ko) Télécharger le fichier
om7b00257_si_001.pdf (513.66 Ko) Télécharger le fichier
Origin : Files produced by the author(s)
Origin : Files produced by the author(s)

Dates and versions

hal-01559206 , version 1 (13-09-2017)

Identifiers

Cite

Hadi Hachem, Antoine Vacher, Vincent Dorcet, Dominique Lorcy. How the Anchoring Site on Two Extended Tetrathiafulvalenes Impacts the Electronic Communication through a Bis(acetylide)ruthenium Linker. Organometallics, 2017, 36 (11), pp.2208-2217. ⟨10.1021/acs.organomet.7b00257⟩. ⟨hal-01559206⟩
85 View
236 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More