Anisyl-, aminophenyl-, and naphthylmethylsilatranes revisited - Université de Rennes Access content directly
Journal Articles Chemistry of Heterocyclic Compounds Year : 2016

Anisyl-, aminophenyl-, and naphthylmethylsilatranes revisited

Yu Wang
Vitalijs Romanovs
  • Function : Author
Jana Spura
  • Function : Author
Lubova Ignatovica
  • Function : Author

Abstract

Three Si-substituted silatranes were synthesized in order to rectify their structure with particular attention to the length of the N-Si intramolecular dative bond. DFT calculations of potential energy profile as a function of the N-Si distance and the structure of HOMO were considered. The latter was found to vary its localization depending on the electron-donating properties of the substituent and the N-Si distance.
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Dates and versions

hal-01395465 , version 1 (10-11-2016)

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Yu Wang, Vitalijs Romanovs, Jana Spura, Lubova Ignatovica, Thierry Roisnel, et al.. Anisyl-, aminophenyl-, and naphthylmethylsilatranes revisited. Chemistry of Heterocyclic Compounds, 2016, 52 (8), pp.546--550. ⟨10.1007/s10593-016-1928-1⟩. ⟨hal-01395465⟩
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