%0 Journal Article %T Anisyl-, aminophenyl-, and naphthylmethylsilatranes revisited %+ Institut des Sciences Chimiques de Rennes (ISCR) %A Wang, Yu %A Romanovs, Vitalijs %A Spura, Jana %A Ignatovica, Lubova %A Roisnel, Thierry %A Jouikov, Viatcheslav %< avec comité de lecture %@ 0009-3122 %J Chemistry of Heterocyclic Compounds %I Springer Verlag %V 52 %N 8 %P 546--550 %8 2016 %D 2016 %R 10.1007/s10593-016-1928-1 %K photoelectron-spectra %K structural features %K silicon-compounds %K cation radicals %K silatranes %K organogermatranes %K pentacoordinate %K assignment %K oxidation %K nitrogen %Z Chemical SciencesJournal articles %X Three Si-substituted silatranes were synthesized in order to rectify their structure with particular attention to the length of the N-Si intramolecular dative bond. DFT calculations of potential energy profile as a function of the N-Si distance and the structure of HOMO were considered. The latter was found to vary its localization depending on the electron-donating properties of the substituent and the N-Si distance. %G English %L hal-01395465 %U https://univ-rennes.hal.science/hal-01395465 %~ UNIV-RENNES1 %~ CNRS %~ INSA-RENNES %~ ENSC-RENNES %~ ISCR %~ SCR-CD %~ SCR_CPM %~ STATS-UR1 %~ UR1-SPM %~ ISCR-PRATS %~ INC-CNRS %~ UR1-UFR-SPM %~ UR1-HAL %~ ISCR-CORINT %~ UR1-SDLM %~ TEST-UNIV-RENNES %~ TEST-UR-CSS %~ UNIV-RENNES %~ INSA-GROUPE %~ ISCR-CORINT1 %~ UR1-MMS %~ ISCR-CORINT3 %~ TEST2-HALCNRS