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Article Dans Une Revue Synthesis: Journal of Synthetic Organic Chemistry Année : 2023

Carbon-Carbon Bond Forming Reactions in Diazines via Transition Metal-Catalyzed C-H Bond Activation

Résumé

An overview of the key achievements concerning carbon-carbon bond-forming process with diazines under transition metal-catalyzed C-H activation is presented. Focus is devoted to those examples in which the C-H functionalization takes place in the diazine or the benzodiazine core because of its relevance in material sciences and as active pharmaceutical ingredients. These metal-catalyzed protocols take benefit from the biased reactivity of the C-H bonds targeted or from the presence of a rationally-designed directing group at proximity of the C-H bond to be functionalized. As such, innovative alkylations, alkenylations, alkynylations, arylations and carboxylations are accomplished within such skeletons in a step- and atom-economy fashion.
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Dates et versions

hal-04167894 , version 1 (03-08-2023)

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Rafael Gramage-Doria, Christian Bruneau. Carbon-Carbon Bond Forming Reactions in Diazines via Transition Metal-Catalyzed C-H Bond Activation. Synthesis: Journal of Synthetic Organic Chemistry, 2023, ⟨10.1055/a-2134-0307⟩. ⟨hal-04167894⟩
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