Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins - Université de Rennes Access content directly
Journal Articles Chemical Communications Year : 2022

Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins

Abstract

Electronic and steric properties of NHC ligands functionalized with porphyrins were investigated. When porphyrins are used as NHCwingtips, nickel(II) in the macrocyle significantly improves the catalytic activity of the neighbouring NHC-Rh(I) complex in the conjugate addition of phenylboronic acid to cyclohexen-2-one.
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Dates and versions

hal-03841395 , version 1 (07-11-2022)

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Ludivine Poyac, Stefano Scoditti, Xavier Dumail, Michel Granier, Sébastien Clément, et al.. Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins. Chemical Communications, In press, ⟨10.1039/D2CC05547C⟩. ⟨hal-03841395⟩
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