1,1'-Diphenyl-bis(silatrane) as the First Structurally Characterized bis(silatrane) - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Koordinatsionnaya Khimiya / Russian Journal of Coordination Chemistry Année : 2022

1,1'-Diphenyl-bis(silatrane) as the First Structurally Characterized bis(silatrane)

Résumé

1,1'-Diphenyl-bis(silatrane) (I) was obtained by the reaction of tris(1,3-dihydroxypropan-2-yl)amine (L) with PhSi(OEt)(3) in toluene. The molecular structure of complex I was established by X-ray diffraction (CIF file CCDC no. 2078347). Study of the redox properties of new bis(silatrane) I demonstrated that its radical ions generated by cyclic voltammetry are stable since the radical center located on the nitrogen atom is sterically protected within the bis(atrane) cage.

Domaines

Chimie
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Dates et versions

hal-03629982 , version 1 (04-04-2022)

Identifiants

Citer

Yu. Wang, D. M. Vakhrusheva, I. V. Krylova, A. Ya. Kozmenkova, E. N. Nikolaevskaya, et al.. 1,1'-Diphenyl-bis(silatrane) as the First Structurally Characterized bis(silatrane). Koordinatsionnaya Khimiya / Russian Journal of Coordination Chemistry, 2022, 48 (2), pp.69-74. ⟨10.1134/S1070328422010079⟩. ⟨hal-03629982⟩
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