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Article Dans Une Revue Tetrahedron Letters Année : 1993

Phosphine-borane complexes; direct use in asymmetric catalysis

Résumé

An easy and soft method of decomplexation of phosphine-borane complexes, by DABCO, allows its use in asymmetric catalytic hydrogenation of double bonds with metal phosphine complexes. Easy decomplexation of phosphine-borane complexes has been shown by obtention of diphenylphosphinoacetaldehyde 2 and by using of DIOP-borane complex 7 in asymmetric catalytic reaction.

Domaines

Chimie

Dates et versions

hal-03409032 , version 1 (29-10-2021)

Identifiants

Citer

Hugues Brisset, Yann Gourdel, Pascal Pellon, Maurice Le Corre. Phosphine-borane complexes; direct use in asymmetric catalysis. Tetrahedron Letters, 1993, 34 (28), pp.4523-4526. ⟨10.1016/0040-4039(93)88075-T⟩. ⟨hal-03409032⟩
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