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Article Dans Une Revue Chemical Communications Année : 2021

Stereospecific synthesis of chiral P-containing polyaromatics based on 7-membered P-rings

Résumé

We present the stereospecific synthesis of helicenoid-based phosphepines (7-membered P-rings) as well as chiral P-containing polycyclic aromatic hydrocarbons. In these systems, an axial to central chirality transfer takes place from the BINAP moiety to the P-atom. The impact of the molecular design on the structure, the (chir)optical (including circularly polarized luminescence) and redox properties are investigated.

Domaines

Chimie organique
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Origine : Publication financée par une institution

Dates et versions

hal-03271992 , version 1 (06-07-2021)

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Paternité - Pas d'utilisation commerciale

Identifiants

Citer

Reka Mokrai, Anabella Mocanu, Matthew Duffy, Thomas Vives, Elsa Caytan, et al.. Stereospecific synthesis of chiral P-containing polyaromatics based on 7-membered P-rings. Chemical Communications, 2021, 57 (59), pp.7256-7259. ⟨10.1039/D1CC02293H⟩. ⟨hal-03271992⟩
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