Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates
Résumé
Two mixed-metal hydride clusters, corresponding to x = 3 and 4, were structurally characterized from a set of atomically precise heptanuclear clusters, CuAg(H){SP(OPr)} (x = 1-6). An interstitial hydride lying at the center of a tricapped tetrahedral cage was located and refined anisotropically by using X-ray data, and its presence acertained by multinuclear NMR spectroscopy and DFT calculations.
Domaines
Matériaux
Fichier principal
Zhong-2020-Hydride-Encapsulated Bimetallic Clusters Supported by 1, 1-Dithiolates.pdf (1.07 Mo)
Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...