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Article Dans Une Revue Chemical Communications Année : 2020

Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates

Résumé

Two mixed-metal hydride clusters, corresponding to x = 3 and 4, were structurally characterized from a set of atomically precise heptanuclear clusters, CuAg(H){SP(OPr)} (x = 1-6). An interstitial hydride lying at the center of a tricapped tetrahedral cage was located and refined anisotropically by using X-ray data, and its presence acertained by multinuclear NMR spectroscopy and DFT calculations.

Domaines

Matériaux
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Dates et versions

hal-02928949 , version 1 (09-11-2020)

Identifiants

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Yu-Jie Zhong, Jian-Hong Liao, Tzu-Hao Chiu, Ying-Yann Wu, Samia Kahlal, et al.. Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates. Chemical Communications, 2020, 56 (65), pp.9300-9303. ⟨10.1039/d0cc03848b⟩. ⟨hal-02928949⟩
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