Generating Skeletal Diversity and Complexity from Boron-Substituted 1,3-Dienes and Enophiles
Résumé
Boron-substituted 1,3-dienes participate in ene reactions to afford new functionalized synthetic intermediates. After evaluating several enophiles as partners, the resulting products have been engaged in multistep sequences involving first a Diels Alder/allylboration process. A variety of skeletally diverse and complex polycyclic heterocycles were thus synthesized, such as tetrahydro-1H-isoindole-1,3(2H)-diones, eight-membered lactones or tricyclic spiro compounds.
Domaines
Chimie organique
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Francois et al-2020-Generating Skeletal Diversity and Complexity from Boron‐Substituted.pdf (2.55 Mo)
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