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Article Dans Une Revue European Journal of Organic Chemistry Année : 2020

Generating Skeletal Diversity and Complexity from Boron-Substituted 1,3-Dienes and Enophiles

Résumé

Boron-substituted 1,3-dienes participate in ene reactions to afford new functionalized synthetic intermediates. After evaluating several enophiles as partners, the resulting products have been engaged in multistep sequences involving first a Diels Alder/allylboration process. A variety of skeletally diverse and complex polycyclic heterocycles were thus synthesized, such as tetrahydro-1H-isoindole-1,3(2H)-diones, eight-membered lactones or tricyclic spiro compounds.

Domaines

Chimie organique
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Dates et versions

hal-02886405 , version 1 (09-07-2020)

Identifiants

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Benjamin François, Ludovic Eberlin, Fabienne Berrée, Andrew Whiting, Bertrand Carboni. Generating Skeletal Diversity and Complexity from Boron-Substituted 1,3-Dienes and Enophiles. European Journal of Organic Chemistry, 2020, 2020 (22), pp.3282-3293. ⟨10.1002/ejoc.202000330⟩. ⟨hal-02886405⟩
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