Phosphine-pyridonate ligands containing octahedral ruthenium complexes: Access to esters and formic acid - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Catalysis Science & Technology Année : 2017

Phosphine-pyridonate ligands containing octahedral ruthenium complexes: Access to esters and formic acid

Résumé

The preparation of three well-defined ruthenium complexes arising from phosphine-pyridon-e/-ate ligands is described. Solvent dependent Lewis acidic species formation was observed with these complexes. Selective formation of acetals or esters from primary alcohols was observed in the presence of these catalysts. Preliminary evaluation of these complexes in the base free hydrogenation of carbon dioxide is also reported. © The Royal Society of Chemistry 2017.

Domaines

Chimie
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Dates et versions

hal-01581224 , version 1 (06-10-2017)

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Citer

A.R. R Sahoo, F. Jiang, Christian Bruneau, G.V.M. V M Sharma, S. Suresh, et al.. Phosphine-pyridonate ligands containing octahedral ruthenium complexes: Access to esters and formic acid. Catalysis Science & Technology, 2017, 7 (31), pp.3492--3498. ⟨10.1039/c7cy00932a⟩. ⟨hal-01581224⟩
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