Improved and General Manganese-Catalyzed N-Methylation of Aromatic Amines Using Methanol - Université de Rennes Access content directly
Journal Articles Chemistry - A European Journal Year : 2017

Improved and General Manganese-Catalyzed N-Methylation of Aromatic Amines Using Methanol

Abstract

A novel lutidine-based manganese PNP-pincer complex has been synthesized for the selective N-methylation of aromatic amines with methanol. Using borrowing hydrogen methodology, a selection of differently functionalized aniline derivatives is selectively methylated in good yields.
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hal-01518033 , version 1 (04-05-2017)

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Jacob Neumann, Saravanakumar Elangovan, Anke Spannenberg, Kathrin Junge, Matthias Beller. Improved and General Manganese-Catalyzed N-Methylation of Aromatic Amines Using Methanol. Chemistry - A European Journal, 2017, 23 (23), pp.5410-5413. ⟨10.1002/chem.201605218⟩. ⟨hal-01518033⟩
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