Unexpected isolation and structural characterization of a redox-active Fe(II) piano-stool complex with an η1-dppe ligand - Université de Rennes Access content directly
Journal Articles Journal of Organometallic Chemistry Year : 2007

Unexpected isolation and structural characterization of a redox-active Fe(II) piano-stool complex with an η1-dppe ligand

Abstract

A new cationic complex [(η2-bipy)(η5-C5Me5)Fe(η1-dppe)][BPh4] featuring a pendant free diphenylphosphine arm has been isolated in good yield after reaction of 2,2′-bipyridine with the known chloro precursor complex (η2-dppe)(η5-C5Me5)FeCl in presence of NaBPh4. This complex which can be envisioned as a new redox-active building-block has been structurally characterized.

Dates and versions

hal-01468977 , version 1 (16-02-2017)

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Cite

Safaa Ibn Ghazala, Frédéric Paul, Loic Toupet, Claude Lapinte. Unexpected isolation and structural characterization of a redox-active Fe(II) piano-stool complex with an η1-dppe ligand. Journal of Organometallic Chemistry, 2007, 692, pp.917-920. ⟨10.1016/j.jorganchem.2006.10.047⟩. ⟨hal-01468977⟩
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