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Journal Articles Chemical Communications Year : 2017

An unexpected copper-catalyzed carbonylative acetylation of amines

Abstract

A novel copper-catalyzed carbonylative acetylation of amines has been developed. With peroxide as the oxidant as well as the methyl source with a copper catalyst under CO pressure, good yields of N-acetyl amides could be obtained. Notably, this is the first example of carbonylative acetylation.
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Dates and versions

hal-01446724 , version 1 (26-01-2017)

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Yahui Li, Changsheng Wang, Fengxiang Zhu, Zechao Wang, Jean-François Soulé, et al.. An unexpected copper-catalyzed carbonylative acetylation of amines. Chemical Communications, 2017, 53 (1), pp.142-144. ⟨10.1039/c6cc08929a⟩. ⟨hal-01446724⟩
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