Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands - Université de Rennes Access content directly
Journal Articles Chemical Communications Year : 2016

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

Olivier Baslé
Loic Toupet
Elsa Caytan
Marc Mauduit
Jeanne Crassous

Abstract

The first helicene-NHC-iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality.
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Dates and versions

hal-01339910 , version 1 (30-06-2016)

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Nora Hellou, Claire Jahier-Diallo, Olivier Baslé, Monika Srebro-Hooper, Loic Toupet, et al.. Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands. Chemical Communications, 2016, 52 (59), pp.9243-9246. ⟨10.1039/C6CC04257K⟩. ⟨hal-01339910⟩
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