Slow magnetic relaxation in unprecedented mono-dimensional coordination polymer of ytterbium involving tetrathiafulvalene-dicarboxylate linker
Résumé
A one-dimensional compd. has been constructed through a YbIII ion and bridging redox-active deprotonated 4,5-bis(carboxylic)-41,51-methyldithiotetrathiafulvene. This polymer displays slow magnetic relaxation due to the planar magnetic anisotropy of the YbIII, which has been exptl. detd.