Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M6Qi8La6]n- octahedral nano-building blocks - Université de Rennes Access content directly
Journal Articles Dalton Transactions Year : 2016

Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M6Qi8La6]n- octahedral nano-building blocks

Abstract

New luminescent poly(methylmethacrylate) (PMMA) nanocomposites with high content of different hexanuclear octahedral cluster building blocks, namely [Mo6I8(C2F5COO6)](2-), [Re6Se8(CN)6](4-) and [W6Cl14](2-) have been prepared by free-radical polymerisation. To do so, cluster complexes bearing a polymerisable ammonium counter-cation have been synthesised. In this way, we demonstrate that ionic assembling is a powerful tool to functionalise easily any type of anionic cluster units to be introduced in a PMMA organic matrix. All samples remain homogeneous, stable during several months, and retain the luminescence properties of the cluster precursor.
No file

Dates and versions

hal-01236442 , version 1 (01-12-2015)

Identifiers

Cite

Maria Amela-Cortes, Yann Molard, Serge Paofai, Anthony Désert, Jean-Luc Duvail, et al.. Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M6Qi8La6]n- octahedral nano-building blocks. Dalton Transactions, 2016, 45 (1), pp.237-245. ⟨10.1039/C5DT03734D⟩. ⟨hal-01236442⟩
130 View
0 Download

Altmetric

Share

Gmail Facebook X LinkedIn More