Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Asian Journal of Organic Chemistry Année : 2015

Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction

Résumé

The palladium-catalyzed C-C bond formation via direct arylation of free-amine-substituted polyfluoroaniline derivs. proceeds in moderate to high yields with a variety of aryl bromides. The nature of the base was found to be crucial to promote the direct arylation with inhibition of the amination reaction.

Domaines

Chimie

Dates et versions

hal-01188225 , version 1 (28-08-2015)

Identifiants

Citer

Abdelilah Takfaoui, Rachid Touzani, Jean-François Soulé, Pierre H. Dixneuf, Henri Doucet. Palladium-Catalysed Direct Arylation using Free-Amine-Substituted Polyfluoroanilines with Inhibition of Amination-Type Reaction. Asian Journal of Organic Chemistry, 2015, 4 (10), pp.1085-1095. ⟨10.1002/ajoc.201500268⟩. ⟨hal-01188225⟩
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