C–C Bond Formation on Activation of Alkynes and Alkenes with (C5R5)Ru Catalysts - Université de Rennes Access content directly
Book Sections Year : 2014

C–C Bond Formation on Activation of Alkynes and Alkenes with (C5R5)Ru Catalysts

Sylvie Dérien
  • Function : Author
  • PersonId : 841551

Abstract

Electron-rich ruthenium(II) catalysts of type (C5R5)XRuL n are used to perform selective carbon–carbon bond formation by combination of simple substrates such as the coupling of functional alkynes and alkenes with a variety of unsaturated molecules (alkynes, diynes, alkenes, dienes) or non-unsaturated molecules such as alcohols or water, often with atom economy. Various selective transformations are developed and can provide access to high multifunctional molecules. These reactions often proceed via an initial oxidative coupling leading to a ruthenacycle intermediate
No file

Dates and versions

hal-01174905 , version 1 (10-07-2015)

Identifiers

Cite

Sylvie Dérien. C–C Bond Formation on Activation of Alkynes and Alkenes with (C5R5)Ru Catalysts. Dixneuf, Pierre H. and Bruneau, Christian (ed). Ruthenium in Catalysis, 48, Springer International Publishing, pp.289--318, 2014, Topics in Organometallic Chemistry, 978-3-319-08481-7, 978-3-319-08482-4. ⟨10.1007/3418_2014_82⟩. ⟨hal-01174905⟩
37 View
0 Download

Altmetric

Share

Gmail Facebook X LinkedIn More