Syntheses of Cu(I) polymetallic assemblies from reaction of ligands bearing the 2,5-bis(2-pyridyl)phosphole fragment with Cu(II) precursors. - Université de Rennes Access content directly
Journal Articles Chemical Communications Year : 2013

Syntheses of Cu(I) polymetallic assemblies from reaction of ligands bearing the 2,5-bis(2-pyridyl)phosphole fragment with Cu(II) precursors.

Abstract

Upon reaction with ligands A, 1 and 3 bearing the 2,5-bis(2-pyridyl)phosphole fragment, an unexpected conversion of Cu(II) metal centers to Cu(I) centers is observed affording either bimetallic complexes bearing a bridging phosphane coordination mode or hexametallic metallacycles.

Domains

Catalysis
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Dates and versions

hal-00878617 , version 1 (30-10-2013)

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Mehdi El Sayed Moussa, Fabian Friess, Wenting Shen, Muriel Hissler, Régis Réau, et al.. Syntheses of Cu(I) polymetallic assemblies from reaction of ligands bearing the 2,5-bis(2-pyridyl)phosphole fragment with Cu(II) precursors.. Chemical Communications, 2013, 49 (55), pp.6158-60. ⟨10.1039/c3cc42955e⟩. ⟨hal-00878617⟩
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