Chemical reactivity of 6-diazo-5-oxo-l-norleucine (DON) catalyzed by metalloporphyrins (Fe,Ru) - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Tetrahedron Année : 2010

Chemical reactivity of 6-diazo-5-oxo-l-norleucine (DON) catalyzed by metalloporphyrins (Fe,Ru)

Résumé

The transfer of the metallocarbene derived from N- and O-protected 6-diazo-5-oxo-l-norleucine (DON) catalyzed by metalloporphyrins undergoes dimerization, cyclopropanation, N-H and S-H insertion reactions, respectively. An efficient and direct synthesis of 5-oxo-l-pipecolic acid from DON is described from unprotected 6-diazo-5-oxo-l-norleucine.

Dates et versions

hal-00869731 , version 1 (04-10-2013)

Identifiants

Citer

Paul Le Maux, Irène Nicolas, Soizic Chevance, Gérard Simonneaux. Chemical reactivity of 6-diazo-5-oxo-l-norleucine (DON) catalyzed by metalloporphyrins (Fe,Ru). Tetrahedron, 2010, 66 (25), pp.4462-4468. ⟨10.1016/j.tet.2010.04.080⟩. ⟨hal-00869731⟩
49 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More