Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C-H bond activation, experimental and theoretical studies on their photoreactivity. - Université de Rennes Access content directly
Journal Articles Chemical Communications Year : 2013

Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C-H bond activation, experimental and theoretical studies on their photoreactivity.

Abstract

The palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclohexene with a variety of heteroarenes gives rise in to a new family of 1,2-di(heteroaryl)perfluorocyclohexenes. These derivatives do not exhibit photoreactivity and this unexpected outcome is explained by calculations demonstrating the lack of reactive isomers.

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hal-00860214 , version 1 (10-09-2014)

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Kedong Yuan, Julien Boixel, Hubert Le Bozec, Abdou Boucekkine, Henri Doucet, et al.. Perfluorocyclohexene bridges in inverse DiArylEthenes: synthesis through Pd-catalysed C-H bond activation, experimental and theoretical studies on their photoreactivity.. Chemical Communications, 2013, 49 (72), pp.7896-8. ⟨10.1039/c3cc43754j⟩. ⟨hal-00860214⟩
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