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Article Dans Une Revue Journal of Physical Chemistry C Année : 2013

Evaluation of MIL-47(V) for CO2-Related Applications

Résumé

Carbon dioxide and methane adsorption has been carried out up to 50 bar on the MIL-47(V) metal–organic framework (MOF) at 303 K. The so-obtained performance has been compared with other well-known MOFs, an activated carbon, and the zeolite NaY both in amount and volume adsorbed scales. In the latter scale, which would be of interest for real applications, the MIL-47(V) shows promising results similar to those of Cu3(BTC)2 or HKUST-1. Operando Infrared experiments have been employed to characterize the strength of the interactions in play. Finally, the CO2/CH4 separation properties have been further predicted using a combination of macroscopic and microscopic modeling approaches. This body of results suggests that this material should be considered for gas separation.
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Dates et versions

hal-00777354 , version 1 (17-01-2013)

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Citer

P. L. Llewellyn, Sandrine Bourrelly, Christelle Vagner, Nicolas Heymans, Hervé Leclerc, et al.. Evaluation of MIL-47(V) for CO2-Related Applications. Journal of Physical Chemistry C, 2013, 117 (2), pp.962. ⟨10.1021/jp308525k⟩. ⟨hal-00777354⟩
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