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Article Dans Une Revue Organometallics Année : 2010

New dipyridylamine ruthenium complexes for transfer hydrogenation of ary ketones in water

Résumé

A new family of cationic organometallic chloro compounds of the type [(arene)Ru(N,N)(Cl)]+ containing N,N-chelating dipyridylamine ligands has been synthesized and isolated as the chloride salts, which are water soluble and stable to hydrolysis. The resulting mononuclear ruthenium complexes catalyze the transfer hydrogenation of aryl ketones in aqueous solution to give the corresponding alcohols with good conversion and interesting recyclability.

Domaines

Catalyse
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Dates et versions

hal-00497843 , version 1 (06-07-2010)

Identifiants

Citer

C. Romain, M. K. Elmkaddem, Loïc Toupet, Cédric Fischmeister, C. M. Thomas, et al.. New dipyridylamine ruthenium complexes for transfer hydrogenation of ary ketones in water. Organometallics, 2010, 29, pp.1992. ⟨10.1021/om100127f⟩. ⟨hal-00497843⟩
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