Facial discrimination in monoarylporphyrins: Synthesis and stereochemical behaviour of bis(ligated) monospirobifluorenylporphyrin ruthenium complexes - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Inorganic Chemistry Communications Année : 2007

Facial discrimination in monoarylporphyrins: Synthesis and stereochemical behaviour of bis(ligated) monospirobifluorenylporphyrin ruthenium complexes

Résumé

Condensation of dipyrromethane, pyrrole-2-carbaldehyde with either 9,9′-spirobifluorene or fluorene aldehyde yields new meso-monosubstituted, β-unsubstituted porphyrins. The large size of spirobifluorene hinders the rotation around the Cmeso-Caryl bond to give, for bis-ligated complexes, two different topological faces

Dates et versions

hal-00191044 , version 1 (23-11-2007)

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Citer

Cyril Poriel, Audrey Martail, Gérard Simonneaux. Facial discrimination in monoarylporphyrins: Synthesis and stereochemical behaviour of bis(ligated) monospirobifluorenylporphyrin ruthenium complexes. Inorganic Chemistry Communications, 2007, 10 (6), pp.627-630. ⟨10.1016/j.inoche.2007.02.006⟩. ⟨hal-00191044⟩
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