<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-05455426</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-02T00:32:11+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Hybrid Ferrocenyl Redox Gold Nanoparticles. Multielectronic Transfer and Ion-Specific Deposition</title>
            <title xml:lang="fr">Nanoparticules d'or redox ferrocényliques hybrides. Transfert multiélectronique et déposition en fonction des ions.</title>
            <author role="aut">
              <persName>
                <forename type="first">Guilhem</forename>
                <surname>Pignol</surname>
              </persName>
              <idno type="halauthorid">2620958-0</idno>
              <affiliation ref="#struct-194938"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Shuai</forename>
                <surname>Liu</surname>
              </persName>
              <idno type="halauthorid">1283019-0</idno>
              <affiliation ref="#struct-304787"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Soizic</forename>
                <surname>Chevance</surname>
              </persName>
              <email type="md5">3993da651cf605c59401166bc4e66eac</email>
              <email type="domain">univ-rennes1.fr</email>
              <idno type="idhal" notation="string">soizic-chevance</idno>
              <idno type="idhal" notation="numeric">751879</idno>
              <idno type="halauthorid" notation="string">41938-751879</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/AAC-4249-2019</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-9699-5943</idno>
              <idno type="IDREF">https://www.idref.fr/083597751</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/AAC-4249-2019</idno>
              <affiliation ref="#struct-194938"/>
            </author>
            <author role="crp">
              <persName>
                <forename type="first">Philippe</forename>
                <surname>Hapiot</surname>
              </persName>
              <email type="md5">5a6d975bba612b82d897cc5cd3592ba8</email>
              <email type="domain">univ-rennes.fr</email>
              <idno type="idhal" notation="numeric">1177055</idno>
              <idno type="halauthorid" notation="string">220730-1177055</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-6730-3570</idno>
              <affiliation ref="#struct-194938"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Philippe</forename>
                <surname>Hapiot</surname>
              </persName>
              <email type="md5">141a17190d20728ede98f81a8a0bd20c</email>
              <email type="domain">univ-rennes1.fr</email>
            </editor>
            <funder>Centre National de la Recherche Scientifique</funder>
            <funder>Université de Rennes 1</funder>
            <funder>Institut de chimie</funder>
            <funder>Université de Rennes</funder>
            <funder>This work was completed in Sciences Chimiques de Rennes, UMR CNRS 6226, Université de Rennes 1, France. Dr Guilhem Pignol was supported by the CNRS/MITI 2021 PhD grant. Dr Shuai Liu’s stay was supported by the Chinese Scholarship Council - Joint Ph.D. Training Program and by the IRP “NanoBioCatChem” joint laboratory between CNRS - Universities - School (ENS-Paris/Rennes 1/Xiamen/Wuhan). Part of this work has been performed using the PRISM core facility (Biogenouest, Univ. Rennes, Univ. Angers, INRAE, CNRS, France). Authors thank Dr Yann Leroux (CNRS, Univ. Rennes, France) and C. Lagrost (CNRS, Univ. Rennes, France) for their help in the synthesis of gold nanoparticles. Prof. D. Astruc (Univ. Bordeaux, France) is greatly thanked for very helpful discussions about preparation and properties of ferrocenyl gold nanoparticles in the presence of different anions.</funder>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2026-01-13 08:14:34</date>
              <date type="whenModified">2026-03-12 03:06:04</date>
              <date type="whenReleased">2026-02-24 14:44:27</date>
              <date type="whenProduced">2025-10-07</date>
              <date type="whenEndEmbargoed">2026-01-13</date>
              <ref type="file" target="https://univ-rennes.hal.science/hal-05455426v1/document">
                <date notBefore="2026-01-13"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://univ-rennes.hal.science/hal-05455426v1/file/Manuscript%20Rev2.pdf" id="file-5455426-4662797">
                <date notBefore="2026-01-13"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="729625">
                <persName>
                  <forename>Philippe</forename>
                  <surname>Hapiot</surname>
                </persName>
                <email type="md5">141a17190d20728ede98f81a8a0bd20c</email>
                <email type="domain">univ-rennes1.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-05455426</idno>
            <idno type="halUri">https://univ-rennes.hal.science/hal-05455426</idno>
            <idno type="halBibtex">pignol:hal-05455426</idno>
            <idno type="halRefHtml">&lt;i&gt;ACS Electrochemistry&lt;/i&gt;, 2025, 1 (11), pp.2424-2431. &lt;a target="_blank" href="https://dx.doi.org/10.1021/acselectrochem.5c00255"&gt;&amp;#x27E8;10.1021/acselectrochem.5c00255&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">ACS Electrochemistry, 2025, 1 (11), pp.2424-2431. &amp;#x27E8;10.1021/acselectrochem.5c00255&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-5455426-4662797"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="UNIV-RENNES1">Université de Rennes 1</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="INSA-RENNES">Institut National des Sciences Appliquées de Rennes</idno>
            <idno type="stamp" n="ENSC-RENNES">Ecole Nationale Supérieure de Chimie de Rennes</idno>
            <idno type="stamp" n="ISCR">INSTITUT DES SCIENCES CHIMIQUES DE RENNES</idno>
            <idno type="stamp" n="SCR_MACSE" corresp="ISCR">Matière Condensée et Systèmes Electroactifs</idno>
            <idno type="stamp" n="SCR_ICMV" corresp="ISCR">Ingénierie Chimique et Molécules pour le Vivant</idno>
            <idno type="stamp" n="UR1-SPM">Université de Rennes 1 - UFR Sciences et Propriétés de la Matière</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="UR1-UFR-SPM">UFR SPM Sciences et Propriétés de la Matière</idno>
            <idno type="stamp" n="UR1-HAL">Publications labos UR1 dans HAL-Rennes 1</idno>
            <idno type="stamp" n="ISCR-CORINT">Chimie ORganique &amp; INTerfaces</idno>
            <idno type="stamp" n="UR1-SDLM">UR1 - publications SDLM</idno>
            <idno type="stamp" n="TEST-UR-CSS">TEST Université de Rennes CSS</idno>
            <idno type="stamp" n="UNIV-RENNES">Université de Rennes</idno>
            <idno type="stamp" n="INSA-GROUPE">Groupe INSA</idno>
            <idno type="stamp" n="CNANO-R" corresp="UNIV-RENNES">C'nano - Rennes</idno>
            <idno type="stamp" n="ISCR-CORINT1" corresp="ISCR">ISCR-CORINT (prénoms complets)</idno>
            <idno type="stamp" n="UR1-MMS">Pôle UnivRennes - Matériaux</idno>
            <idno type="stamp" n="MITI">MITI</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Hybrid Ferrocenyl Redox Gold Nanoparticles. Multielectronic Transfer and Ion-Specific Deposition</title>
                <title xml:lang="fr">Nanoparticules d'or redox ferrocényliques hybrides. Transfert multiélectronique et déposition en fonction des ions.</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Guilhem</forename>
                    <surname>Pignol</surname>
                  </persName>
                  <idno type="halauthorid">2620958-0</idno>
                  <affiliation ref="#struct-194938"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Shuai</forename>
                    <surname>Liu</surname>
                  </persName>
                  <idno type="halauthorid">1283019-0</idno>
                  <affiliation ref="#struct-304787"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Soizic</forename>
                    <surname>Chevance</surname>
                  </persName>
                  <email type="md5">3993da651cf605c59401166bc4e66eac</email>
                  <email type="domain">univ-rennes1.fr</email>
                  <idno type="idhal" notation="string">soizic-chevance</idno>
                  <idno type="idhal" notation="numeric">751879</idno>
                  <idno type="halauthorid" notation="string">41938-751879</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/AAC-4249-2019</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-9699-5943</idno>
                  <idno type="IDREF">https://www.idref.fr/083597751</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/AAC-4249-2019</idno>
                  <affiliation ref="#struct-194938"/>
                </author>
                <author role="crp">
                  <persName>
                    <forename type="first">Philippe</forename>
                    <surname>Hapiot</surname>
                  </persName>
                  <email type="md5">5a6d975bba612b82d897cc5cd3592ba8</email>
                  <email type="domain">univ-rennes.fr</email>
                  <idno type="idhal" notation="numeric">1177055</idno>
                  <idno type="halauthorid" notation="string">220730-1177055</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-6730-3570</idno>
                  <affiliation ref="#struct-194938"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">1005031</idno>
                <idno type="issn">2997-0571</idno>
                <idno type="eissn">2997-0571</idno>
                <title level="j">ACS Electrochemistry</title>
                <imprint>
                  <biblScope unit="volume">1</biblScope>
                  <biblScope unit="issue">11</biblScope>
                  <biblScope unit="pp">2424-2431</biblScope>
                  <date type="datePub">2025-10-07</date>
                  <date type="dateEpub">2025-10-07</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1021/acselectrochem.5c00255</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Electrochemistry</term>
                <term xml:lang="en">BARF</term>
                <term xml:lang="en">ultramicroelectrode</term>
                <term xml:lang="en">Electrochemistry</term>
                <term xml:lang="en">Ferrocenyl Gold nanoparticle</term>
                <term xml:lang="en">Ferrocenyl Gold nanoparticle solubility BARF ultramicroelectrode</term>
                <term xml:lang="en">solubility</term>
              </keywords>
              <classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>&lt;div&gt;&lt;p&gt;The electrochemistry of alkyl-ferrocene gold nanoparticles including varying percentages of ferrocenyl ligands was examined in steady conditions for their interest as multielectronic redox systems in solution. By selecting anion of the electrolyte and solvent, it was possible to obtain a negligible deposition of the nanoparticles regardless of their composition. We found that CH 2 Cl 2 as a solvent with tetrabutylammonium tetrakis(3,5bis(trifluoromethyl)phenyl) borate (NBu 4 BarF) as electrolyte leads to a diffusive response in the ~1 micromolar solubility limits (up to ~10 -4 molar equivalent of ferrocene moieties) in steady state condition on a 10 m diameter microelectrode. Detailed characterizations of the nanoparticles using TEM, 1H NMR (1D and 2D DOSY) were used to get an average molecular formula and diffusion coefficient of the different species. Using these values, estimation of the plateau diffusion current shows a good agreement with experimental data but also that only 50% of the ferrocenyl moieties attached onto the nanoparticles contributes to the current.&lt;/p&gt;&lt;/div&gt;</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-194938" status="VALID">
          <idno type="IdRef">161775241</idno>
          <idno type="ISNI">0000 0004 0385 6584</idno>
          <idno type="RNSR">200612270R</idno>
          <idno type="ROR">https://ror.org/00adwkx90</idno>
          <idno type="Wikidata">Q30261343</idno>
          <orgName>Institut des Sciences Chimiques de Rennes</orgName>
          <orgName type="acronym">ISCR</orgName>
          <date type="start">2006-01-01</date>
          <desc>
            <address>
              <addrLine>Campus de Beaulieu - Bât. 10 Avenue du Général Leclerc 35042 Rennes Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://iscr.univ-rennes.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-105160" type="direct"/>
            <relation active="#struct-117606" type="direct"/>
            <relation active="#struct-301232" type="indirect"/>
            <relation active="#struct-300373" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR6226" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-304787" status="VALID">
          <idno type="ROR">https://ror.org/00mcjh785</idno>
          <orgName>Xiamen University</orgName>
          <desc>
            <address>
              <country key="CN"/>
            </address>
          </desc>
        </org>
        <org type="institution" xml:id="struct-105160" status="VALID">
          <idno type="IdRef">26693823X</idno>
          <idno type="ROR">https://ror.org/015m7wh34</idno>
          <orgName>Université de Rennes</orgName>
          <orgName type="acronym">UR</orgName>
          <desc>
            <address>
              <addrLine>Campus de Beaulieu, 263 avenue Général Leclerc, CS 74205, 35042 RENNES CEDEX</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-rennes.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-117606" status="VALID">
          <idno type="ROR">https://ror.org/04xaa4j22</idno>
          <orgName>Institut National des Sciences Appliquées - Rennes</orgName>
          <orgName type="acronym">INSA Rennes</orgName>
          <desc>
            <address>
              <addrLine>20, avenue des Buttes de Coësmes - CS 70839 - 35708 Rennes cedex 7</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.insa-rennes.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301232" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301232" status="VALID">
          <idno type="IdRef">162105150</idno>
          <orgName>Institut National des Sciences Appliquées</orgName>
          <orgName type="acronym">INSA</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300373" status="VALID">
          <idno type="ROR">https://ror.org/01h0ffh48</idno>
          <orgName>Ecole Nationale Supérieure de Chimie de Rennes</orgName>
          <orgName type="acronym">ENSCR</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>