Phase dependence and mechanical and thermal ductility of the luminescence properties of tetranuclear Cu( i ) metallacycle assemblies stabilized by ditopic organo-pnictogen (P,As) ligands
Résumé
A tetranuclear Cu( i ) metallacycle stabilized by ditopic organo-pnictogen (P,As) ligands presents stimuli-sensitive luminescence whose origin is compared with those based on congener (P,P) ligands, revealing competitive effects involving solid-state packing and spin–orbit coupling.
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