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Article Dans Une Revue Inorganic Chemistry Année : 2023

Extending Chirality in Group XIV Metallatranes

Résumé

The syntheses of the racemic amino alcohol racN(CH2CMe2OH)(CMe2CH2OH)(CH2CHMeOH) (L22'1*H3, 2) and its representative N(CH2CMe2OH)(CMe2CH2OH)(CH2C-(R)HMeOH) (L22'1RH3, 3) with the stereogenic carbon center being R-configured are reported. Also reported are the stannatranes L22'1*SnOt-Bu (4) L22'1RSnOt-Bu (6) and germatranes L22'1*GeOEt (5) and L22'1RGeOEt (7) as well as the trinuclear tin oxocluster [(mu 3-O)(mu 3-O-t-Bu){SnL22'1R}3] (8). NMR and IR spectroscopy, electrospray ionization mass spectrometry (ESI MS), and single crystal X-ray diffraction analysis characterize these compounds. Computational studies accompany the experimental work and help understand the diastereoselectivity observed in the course of the metallatrane syntheses.
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Dates et versions

hal-04115414 , version 1 (02-06-2023)

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Citer

Britta Glowacki-Pallach, Michael Lutter, Dieter Schollmeyer, Wolf Hiller, Viatcheslav Jouikov, et al.. Extending Chirality in Group XIV Metallatranes. Inorganic Chemistry, 2023, 62 (20), pp.7662-7680. ⟨10.1021/acs.inorgchem.2c04242⟩. ⟨hal-04115414⟩
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