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Article Dans Une Revue Inorganic Chemistry Frontiers Année : 2022

Exploring the boundaries of ferrocenesulfonyl fluoride chemistry

Résumé

Ferrocenesulfonyl fluorides represent a new subfamily of metallocenes barely explored. Here, we describe how the use of deprotolithiation-electrophilic trapping sequences and 'halogen dance' reactions can afford up to 1,2,3,4,5-hetero pentasubstituted derivatives. While the orthogonal reactivity of ferrocenesulfonyl fluorides was demonstrated in a variety of transformations, SuFEx chemistry afforded various sulfur-based ferrocene derivatives. The electrochemical behaviour of many polysubstituted derivatives was studied and discussed as well as weak interactions identified in the solid state.

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hal-03827534 , version 1 (24-10-2022)

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William Erb, Jean-Pierre Hurvois, Yury S. Halauko, Vadim E Matulis, Thierry Roisnel. Exploring the boundaries of ferrocenesulfonyl fluoride chemistry. Inorganic Chemistry Frontiers, 2022, ⟨10.1039/d2qi01854c⟩. ⟨hal-03827534⟩
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