Spiro-configured dibenzosuberene compounds as deep-blue emitters for organic light-emitting diodes with a CIEy of 0.04 - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Materials Chemistry Frontiers Année : 2022

Spiro-configured dibenzosuberene compounds as deep-blue emitters for organic light-emitting diodes with a CIEy of 0.04

Résumé

Deep blue electroluminescence is highly required for organic light-emitting diode (OLED) technology. However, designing fluorophores displaying adequate CIE coordinates and particularly a low CIEy is far from an easy task. We report in this work the synthesis, the physico-chemical properties and the application of deep blue emitters constructed using the dibenzosuberene (DBS) molecular fragment in OLEDs. Three emitters, SPA-DBS, SIA-DBS and SQPTZ-DBS, have been constructed following a similar molecular design strategy that is the spiro connection of an electron rich unit, namely N-phenylacridine (PA), indoloacridine (IA) or quinolinophenothiazine (QPTZ) to the DBS core. The PA, IA and QPTZ fragments are known to be efficient hole injecters due to their strong electron-rich character. Through a structure/property relationship study, we analyse the electrochemical, photophysical and thermal behaviours of these three emitters. When used as an emitter in an OLED, a deep-blue emission with CIE of (0.16, 0.04) is obtained with SPA-DBS, reaching an EQE of ca. 1% and a V-on of 4 V. The CIEy coordinate of 0.04 appears to be particularly low and fits the NSTC, ITU and EBU standards.

Domaines

Chimie organique
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Dates et versions

hal-03715050 , version 1 (20-09-2022)

Licence

Paternité - Pas d'utilisation commerciale

Identifiants

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Clement Brouillac, Wan-Shan Shen, Joelle Rault-Berthelot, Olivier Jeannin, Cassandre Quinton, et al.. Spiro-configured dibenzosuberene compounds as deep-blue emitters for organic light-emitting diodes with a CIEy of 0.04. Materials Chemistry Frontiers, 2022, 6 (13), pp.1803-1813. ⟨10.1039/d2qm00287f⟩. ⟨hal-03715050⟩
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