Switchable Phase Transition from Crystalline to Amorphous States of Cadmium Sulfate Octahydrate Single Crystals by Shock Waves - Université de Rennes Accéder directement au contenu
Article Dans Une Revue physica status solidi (b) Année : 2022

Switchable Phase Transition from Crystalline to Amorphous States of Cadmium Sulfate Octahydrate Single Crystals by Shock Waves

Résumé

Even slight changes occurring in the lattice positions of solid materials enforced by the external forces may give rise to remarkable results in the crystallographic nature. The materials which undergo phase-change without modifying their overall chemistry are the prominent candidates to be the driving forces for the applications involving phase transitions. In the present context, the authors present and demonstrate the switchable phase transition occurring between crystalline and amorphous nature of cadmium sulfate octahydrate single crystals (3CdSO(4)center dot 8H(2)O) impacted by shock waves with which the transition is authenticated via diffraction, vibrational and optical spectroscopic techniques such as powder X-ray diffractometry, Raman and UV-Vis spectral analyses. Based on the results attained from diffraction and spectroscopic analyses, it is observed that the switchable phase transition sequence is crystalline-crystalline-amorphous-crystalline-crystalline with respect to the control, one, two, three, and four shock-wave-loaded conditions, respectively. Due to the outstanding switching behavior, the title material is strongly suggested for the applications of molecular switching and optical data storage systems.
Fichier principal
Vignette du fichier
Sivakumar et al. - 2022 - Switchable Phase Transition from Crystalline – Amo.pdf (1.52 Mo) Télécharger le fichier
Sivakumar_pssb202100662-sup-0001-suppdata-s1.pdf (396.32 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03657582 , version 1 (11-05-2022)

Licence

Paternité - Pas d'utilisation commerciale

Identifiants

Citer

Aswathappa Sivakumar, Sathiyadhas Sahaya Jude Dhas, Kondaveeti Showrilu, Paramasiva Sivaprakash, Raju Suresh Kumar, et al.. Switchable Phase Transition from Crystalline to Amorphous States of Cadmium Sulfate Octahydrate Single Crystals by Shock Waves. physica status solidi (b), 2022, pp.2100662. ⟨10.1002/pssb.202100662⟩. ⟨hal-03657582⟩
30 Consultations
41 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More