From ferrocene to 1,2,3,4,5-pentafluoroferrocene: halogen effect on the properties of metallocene
Résumé
The sequentially fluorinated ferrocenes (1-, 1,2-di, 1,2,3-tri, 1,2,3,4-tetra and 1,2,3,4,5-pentafluoroferrocene) have been synthesized from ferrocene. Rather than a 'perfluoro' effect, experimental and computational analysis of the complete series robustly demonstrates a linear additive effect of fluorine on the electrochemical and spectroscopic properties of ferrocene.
Domaines
Chimie
Fichier principal
Erb et al-2021-From ferrocene to 1,2,3,4,5-pentafluoroferrocene halogen .pdf (1.02 Mo)
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SI-From ferrocene to 1,2,3,4,5-pentafluoroferrocene halogen effect on the properties of metallocenes HAL.pdf (2.99 Mo)
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