Triple-Decker Sandwich Complexes of Tungsten with Planar and Puckered Middle Decks
Résumé
A triple-decker complex of tungsten, [(Cp*W){μ-η:η-BHCo(CO)}(H)] (; Cp* = η-CMe), with a planar middle deck has been isolated by thermolysis of an in situ formed intermediate from the reaction of Cp*WCl and LiBH with Co(CO). In addition, we have also isolated another triple-decker complex, [(Cp*W){μ-η:η-BHFe(CO)}(H)] (), having a puckered central ring, from a similar reaction with Fe(CO). Clusters and are unprecedented examples of a triple-decker complex having a 24-valence electron with bridging hydrogen atoms.
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Bag et al - 2021 - Triple-Decker Sandwich Complexes of Tungsten.pdf (1.43 Mo)
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Bag_ic0c03411_si_001.pdf (1.85 Mo)
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Origine : Fichiers produits par l'(les) auteur(s)