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Article Dans Une Revue European Polymer Journal Année : 2020

Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers

Résumé

This review highlights recent progress in the synthesis and application of vinyl ethers (VEs) as monomers for modern homo- and co-polymerization processes. VEs can be easily prepared using a number of traditional synthetic protocols including a more sustainable and straightforward manner by reacting gaseous acetylene or calcium carbide with alcohols. The remarkably tunable chemistry of VEs allows designing and obtaining polymers with well-defined structures and controllable properties. Both VE homopolymerization and copolymerization systems are considered, and specific emphasis is given to the novel initiating systems and to the methods of stereocontrol.
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Dates et versions

hal-02931999 , version 1 (11-09-2020)

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E. Kirillov, K. Rodygin, Valentine P. Ananikov. Recent advances in applications of vinyl ether monomers for precise synthesis of custom-tailored polymers. European Polymer Journal, 2020, 136, pp.109872. ⟨10.1016/j.eurpolymj.2020.109872⟩. ⟨hal-02931999⟩
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