%0 Journal Article %T Use of calixarenes bearing diazonium groups for the development of robust monolayers with unique tailored properties %+ Université libre de Bruxelles (ULB) %+ Laboratoire de Chimie et de Biochimie Pharmacologiques et Toxicologiques (LCBPT - UMR 8601) %+ Institut des Sciences Chimiques de Rennes (ISCR) %A Troian-Gautier, Ludovic %A Mattiuzzi, Alice %A Reinaud, Olivia %A Lagrost, Corinne %A Jabin, Ivan %Z Fonds De La Recherche Scientifique - FNRS %< avec comité de lecture %@ 1477-0520 %J Organic & Biomolecular Chemistry %I Royal Society of Chemistry %V 18 %N 19 %P 3624-3637 %8 2020-05-20 %D 2020 %R 10.1039/d0ob00070a %M 32154553 %Z Chemical SciencesJournal articles %X Surface modification represents an active field of research that finds applications, amongst others, in the development of medical devices, sensors and biosensors, anti-biofouling materials, self-cleaning surfaces, surfaces with controlled wettability, corrosion resistance, heterogeneous catalysis and microelectronics. For some applications, surface functionalization with a nanometric-size monolayer is desired. In this review, efforts to covalently functionalize a wide array of surfaces with calixarenes bearing diazonium groups are described. More specifically, methodologies to obtain monolayers of calix[4 or 6]arene derivatives on conductive, semi-conductive or insulating surfaces as well as on nanoparticles are presented. The main advantages of this general surface modification strategy (i.e. formation of true monolayers that can be post-functionalized, high robustness and control over the composition of the calixarene-based coating) and its current scope of applications and future challenges are discussed. %G English %2 https://univ-rennes.hal.science/hal-02533164/document %2 https://univ-rennes.hal.science/hal-02533164/file/Troian-Gautier-2020-Use%20of%20calixarenes%20bearing%20diazonium%20groups%20for%20the%20development%20of%20robust%20monolayers%20with%20unique%20tailored%20properties%20.pdf %L hal-02533164 %U https://univ-rennes.hal.science/hal-02533164 %~ UNIV-RENNES1 %~ CNRS %~ INSA-RENNES %~ ENSC-RENNES %~ ISCR %~ SCR_MACSE %~ STATS-UR1 %~ UR1-SPM %~ INC-CNRS %~ UR1-UFR-SPM %~ UR1-HAL %~ UR1-SDLM %~ TEST-UR-CSS %~ UNIV-RENNES %~ INSA-GROUPE %~ CNANO-R %~ UNIV-PARIS %~ UNIVERSITE-PARIS %~ UP-SCIENCES %~ TEST-HALCNRS %~ UR1-MMS %~ TEST2-HALCNRS