Use of calixarenes bearing diazonium groups for the development of robust monolayers with unique tailored properties - Université de Rennes Access content directly
Journal Articles Organic & Biomolecular Chemistry Year : 2020

Use of calixarenes bearing diazonium groups for the development of robust monolayers with unique tailored properties

Ludovic Troian-Gautier
Corinne Lagrost
Ivan Jabin

Abstract

Surface modification represents an active field of research that finds applications, amongst others, in the development of medical devices, sensors and biosensors, anti-biofouling materials, self-cleaning surfaces, surfaces with controlled wettability, corrosion resistance, heterogeneous catalysis and microelectronics. For some applications, surface functionalization with a nanometric-size monolayer is desired. In this review, efforts to covalently functionalize a wide array of surfaces with calixarenes bearing diazonium groups are described. More specifically, methodologies to obtain monolayers of calix[4 or 6]arene derivatives on conductive, semi-conductive or insulating surfaces as well as on nanoparticles are presented. The main advantages of this general surface modification strategy (i.e. formation of true monolayers that can be post-functionalized, high robustness and control over the composition of the calixarene-based coating) and its current scope of applications and future challenges are discussed.
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Dates and versions

hal-02533164 , version 1 (07-05-2020)

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Ludovic Troian-Gautier, Alice Mattiuzzi, Olivia Reinaud, Corinne Lagrost, Ivan Jabin. Use of calixarenes bearing diazonium groups for the development of robust monolayers with unique tailored properties. Organic & Biomolecular Chemistry, 2020, 18 (19), pp.3624-3637. ⟨10.1039/d0ob00070a⟩. ⟨hal-02533164⟩
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