%0 Journal Article %T Palladium-catalyzed successive C-H bond arylations and annulations toward the pi-extension of selenophene-containing aromatic skeletons %+ Institut des Sciences Chimiques de Rennes (ISCR) %A Shi, Xinzhe %A Mao, Shuxin %A Roisnel, Thierry %A Doucet, Henri %A Soulé, Jean-François %Z ANR [ANR-16-CE07-0001] %< avec comité de lecture %@ 2052-4129 %J Organic Chemistry Frontiers %I Royal Society of Chemistry %V 6 %N 14 %P 2398-2403 %8 2019-07-21 %D 2019 %R 10.1039/c9qo00218a %Z Chemical SciencesJournal articles %X A modular approach for the synthesis of planar pi-extended selenium containing molecules from selenophene has been developed. Different combinations of Pd-catalyzed desulfitative C-H bond arylations with (2-bromo)arylsulfonyl chlorides and Pd-catalyzed intra- or/and inter-molecular C-H bond arylations with aryl bromides allowed the extension of the selenophene-containing aromatic skeleton at the [b]-, [c]- or [bd]-junctions to give phenanthro[b]selenophenes, phenanthro[c]selenophenes or diphenanthro[bd]selenophenes. %G English %2 https://univ-rennes.hal.science/hal-02278420/document %2 https://univ-rennes.hal.science/hal-02278420/file/Soule_et%20al_Palladium-Catalyzed%20Successive%20C%E2%80%93H%20Bond%20Arylations_accepted.pdf %L hal-02278420 %U https://univ-rennes.hal.science/hal-02278420 %~ UNIV-RENNES1 %~ CNRS %~ INSA-RENNES %~ ENSC-RENNES %~ ISCR %~ SCR-CD %~ SCR_OMC2012 %~ ISCR-OMC %~ STATS-UR1 %~ UR1-SPM %~ ISCR-PRATS %~ INC-CNRS %~ UR1-UFR-SPM %~ UR1-HAL %~ UR1-SDLM %~ TEST-UR-CSS %~ UNIV-RENNES %~ INSA-GROUPE %~ TEST-HALCNRS %~ ANR %~ UR1-MMS %~ TEST2-HALCNRS