Stereochemical Study of Puna’auic Acid, an Allenic Fatty Acid from the Eastern Indo-Pacific Cyanobacterium Pseudanabaena sp - Université de Rennes Accéder directement au contenu
Article Dans Une Revue Organic Letters Année : 2018

Stereochemical Study of Puna’auic Acid, an Allenic Fatty Acid from the Eastern Indo-Pacific Cyanobacterium Pseudanabaena sp

Kevin Calabro
Mayalen Zubia
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Grégory Genta-Jouve
Olivier Thomas
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Résumé

The isolation and structure elucidation of puna'auic acid, an allenic fatty acid isolated from a marine cyanobacterium, is described. All configurations were first assessed through molecular modeling of NMR and ECD spectra and then confirmed through a straightforward enantioselective total synthesis of puna'auic acid featuring a key reductive opening of a propargylic epoxide.
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Dates et versions

hal-02145235 , version 1 (02-06-2019)

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Emmanuel Roulland, Hiren Solanki, Kevin Calabro, Mayalen Zubia, Grégory Genta-Jouve, et al.. Stereochemical Study of Puna’auic Acid, an Allenic Fatty Acid from the Eastern Indo-Pacific Cyanobacterium Pseudanabaena sp. Organic Letters, 2018, 20 (8), pp.2311-2314. ⟨10.1021/acs.orglett.8b00654⟩. ⟨hal-02145235⟩
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