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Article Dans Une Revue Journal of Organic Chemistry Année : 2019

Synthesis, optical and redox properties of regioisomeric benzoheterocycles-fused pyrene

Résumé

A new synthetic route toward the synthesis of benzo[b]phospholes-and benzo[b]siloles-fused pyrenes using a transition metal-catalyzed C-H bond activation is described. The compounds were fully characterized including X-ray dif-fraction. A combined experimental and theoretical study shows that both the heteroa-tom and the substitution pattern impact the optical and redox properties.

Domaines

Chimie organique
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Dates et versions

hal-01971375 , version 1 (07-01-2019)

Identifiants

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Anabella Mocanu, Rózsa Szűcs, Elsa Caytan, Thierry Roisnel, Vincent Dorcet, et al.. Synthesis, optical and redox properties of regioisomeric benzoheterocycles-fused pyrene. Journal of Organic Chemistry, 2019, 84 (2), pp.957-962. ⟨10.1021/acs.joc.8b02884⟩. ⟨hal-01971375⟩
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