Synthesis, optical and redox properties of regioisomeric benzoheterocycles-fused pyrene
Résumé
A new synthetic route toward the synthesis of benzo[b]phospholes-and benzo[b]siloles-fused pyrenes using a transition metal-catalyzed C-H bond activation is described. The compounds were fully characterized including X-ray dif-fraction. A combined experimental and theoretical study shows that both the heteroa-tom and the substitution pattern impact the optical and redox properties.
Domaines
Chimie organique
Origine : Fichiers produits par l'(les) auteur(s)
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