Stable lead(II) boroxides
Résumé
The first examples of lead(ii) boroxides, [Pb(OB{CH(SiMe3)2}2)2] (1) and [{N^C}PbOB{CH(SiMe3)2}2] (5; N^C = 2-Me2NCH2C6H4), were prepared via simple protocols. These structurally characterised compounds are stable and, unlike lead(ii) alkoxides and siloxides, do not trigger uncontrolled formation of lead(ii) oxoclusters.
Domaines
Chimie
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Pb(II)-boroxides_CC-COM-03-2018-002459_R1_Manuscript.pdf (803.54 Ko)
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