%0 Journal Article %T Adaptive Coordination-Driven Supramolecular Syntheses toward New Polymetallic Cu(I) Luminescent Assemblies %+ Institut des Sciences Chimiques de Rennes (ISCR) %+ The University of Hong Kong (HKU) %A Evariste, Sloane %A Khalil, Ali Moustafa %A Moussa, Mehdi Elsayed %A Chan, Alan Kwun-Wa %A Hong, Eugene Yau-Hin %A Wong, Hok-Lai %A Le Guennic, Boris %A Calvez, Guillaume %A Costuas, Karine %A Yam, Vivian Wing-Wah %A Lescop, Christophe %Z Agence Nationale de la Recherche %Z HKU 17334216, Research Grants Council, University Grants Committee %Z University of Hong Kong %Z University Research Committee, University of Hong Kong %Z Ministère de l'Enseignement Supérieur et de la Recherche %Z AoE/P-03/08, University Grants Committee %Z Centre National de la Recherche Scientifique %Z Alexander von Humboldt-Stiftung %< avec comité de lecture %@ 0002-7863 %J Journal of the American Chemical Society %I American Chemical Society %V 140 %N 39 %P 12521-12526 %8 2018-10-03 %D 2018 %R 10.1021/jacs.8b06901 %M 30049208 %Z Chemical SciencesJournal articles %X A thermally activated delayed fluorescence (TADF) tetrametallic Cu(I) metallacycle A behaves as a conformationally adaptive preorganized precursor to afford, through straightforward and rational coordination-driven supramolecular processes, a variety of room-temperature solid-state luminescent polymetallic assemblies. Reacting various cyano-based building blocks with A, a homometallic Cu(I) 1D-helical coordination polymer C and CuM discrete circular heterobimetallic assemblies D (M = Ni, Pd, Pt) are obtained. Their luminescence behaviors are studied, revealing notably the crucial impact of the spin-orbit coupling offered by the central M metal center on the photophysical properties of the heterobimetallic D derivatives. %G English %2 https://univ-rennes.hal.science/hal-01862466/document %2 https://univ-rennes.hal.science/hal-01862466/file/Evariste_Adaptive%20Coordination-Driven.pdf %L hal-01862466 %U https://univ-rennes.hal.science/hal-01862466 %~ UNIV-RENNES1 %~ CNRS %~ INSA-RENNES %~ ENSC-RENNES %~ SCR-MI-INSA %~ ISCR %~ SCR_OMC2012 %~ ISCR-CTI %~ ISCR-CSM %~ STATS-UR1 %~ UR1-SPM %~ GENCI %~ INC-CNRS %~ UR1-UFR-SPM %~ UR1-HAL %~ UR1-SDLM %~ TEST-UR-CSS %~ UNIV-RENNES %~ INSA-GROUPE %~ ISCR-CSM-INSA %~ TEST-HALCNRS %~ ANR %~ UR1-MMS %~ TEST2-HALCNRS