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Journal Articles Organometallics Year : 2017

Efficient Iridium Catalysts for Base-Free Hydrogenation of Levulinic Acid

Abstract

The synthesis and characterization of new dicationic ruthenium and iridium complexes bearing a dipyridylamine ligand (dpa) is reported. These complexes display an unusual zwitterionic molecular structure in the solid state. The iridium complex [Cp*Ir(dpa)(OSO 3)] Ir1 was found to be very efficient in base free hydrogenation of levulinic acid into γ-valerolactone (GVL). TON
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Dates and versions

hal-01614777 , version 1 (28-03-2022)

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S. Wang, H. Huang, V. Dorcet, T. Roisnel, Christian Bruneau, et al.. Efficient Iridium Catalysts for Base-Free Hydrogenation of Levulinic Acid. Organometallics, 2017, 36 (16), pp.3152-3162. ⟨10.1021/acs.organomet.7b00503⟩. ⟨hal-01614777⟩
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