Porphyrin symmetry and chiral catalysis in water
Résumé
Chiral metalloporphyrins (ruthenium, iron and manganese) have been developed in solution. Both effective chiral recognition and asymmetric catalysis using optically active macrocycles were observed. Asymmetric oxidation and carbene transfer showed potential pharmaceutical applications.
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Simonneaux-2017_2_161-240_Symmetry-Culture-and-Science.pdf (59.69 Ko)
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