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Article Dans Une Revue Applied Organometallic Chemistry Année : 2004

Ionization potentials of heteroalkenes: A comparative study

Résumé

Methanimine, methylenephosphine and methylenearsine have been prepared in the gas phase and the gaseous flow has been analyzed by spectroscopy. Photoelectron spectra have been recorded and we report here a comparative study on these spectra. This comparison has been extended to the corresponding derivatives with a triple bond: hydrogen cyanide and methylidynephosphine. Estimation by theoretical calculations of the ionization potentials of the unknown methylidynearsine has been proposed. Copyright © 2004 John Wiley & Sons, Ltd.

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hal-01566350 , version 1 (20-07-2017)

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Anna Chrostowska, V. Lemierre, Alain Dargelos, Jean-Marc Sotiropoulos, J.-C. Guillemin. Ionization potentials of heteroalkenes: A comparative study. Applied Organometallic Chemistry, 2004, 18 (12), pp.690--693. ⟨10.1002/aoc.640⟩. ⟨hal-01566350⟩
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