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Article Dans Une Revue Angewandte Chemie International Edition Année : 2004

First synthesis and characterization by mass spectrometry and UV-photoelectron spectroscopy of methylenearsane

Résumé

In a vacuum gas-solid reaction (VGSR; see scheme), the kinetically unstable methylenearsane was synthesized by dehydrohalogenation of gaseous chloromethylarsane on solid sodium carbonate and characterized in the gas phase by mass spectrometry and UV photoelectron spectroscopy. A new approach to theoretically evaluate ionization potentials is also demonstrated.

Dates et versions

hal-01566347 , version 1 (20-07-2017)

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Anna Chrostowska, Alain Dargelos, V. Lemierre, Jean-Marc Sotiropoulos, P. Guenot, et al.. First synthesis and characterization by mass spectrometry and UV-photoelectron spectroscopy of methylenearsane. Angewandte Chemie International Edition, 2004, 43 (7), pp.873--875. ⟨10.1002/anie.200352445⟩. ⟨hal-01566347⟩
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